Preheat oven to 350° F. Grease three 8" cake rounds, line with parchment rounds (to make it easy to release), and spray again. (You can also make as four layer 6" cake, two 9" cakes, a sheet cake, or cupcakes - just adjust baking time) In a large bowl sift together the all purpose flour*, cornstarch, baking powder, baking soda, and salt. Set aside. Measure out the buttermilk with lemon juice and set aside.
In a stand mixer, combine the softened butter, sugar, zest, together and mix for a couple minutes until light and fluffy. Add eggs, mixing briefly after each one. Add vanilla extract. Scrape the bowl as needed and mix together until everything is incorporated.
Add the dry ingredients, alternating with the buttermilk/lemon mixture. Just be careful not to over mix.
Divide the batter into your 3 prepared pans (or alternate baking dish of choice).(I get about 12 oz batter in each of the four 6" pans and about 18 oz of batter in each of the three 8" pans.) Bake for 22-25 minutes until a few moist crumbs are left on the toothpick. Remember, the cake continues to bake after you take it out of the oven. Remove from oven and set aside.
Sugar syrup: While cakes are cooling, make the sugar syrup in a small sauce pan on the stove. Combine the sugar, lemon juice, and water. Simmer and stir until sugar is dissolved, then immediately remove from heat.
Transfer cake layers on cooling racks and gently poke lots of holes in the top of each layer with a toothpick. Using a pastry brush (or spoon), generously brush layers with the lemon syrup. You may not use all of the syrup - that's okay. Let cakes cool completely before wrapping up or frosting.